Russia, as expected, vetoed a UN Security Council resolution that deplored "in the strongest terms" the country's "aggression" against Ukraine and demanded the immediate withdrawal of its troops.
Eleven of the council's 15 members voted for the motion, which was co-written by the United States and Albania. China, India and the UAE abstained.
The resolution was always doomed to fail because of Moscow's veto power as a permanent member of the council.
However, the debate offered member nations an opportunity to voice condemnation of President Vladimir Putin's decision to launch a full-scale offensive against Russia's neighbour.
'Russia is isolated'
"Let me make one thing clear," US Ambassador to the UN Linda Thomas-Greenfield said after the vote. "Russia, you can veto this resolution, but you cannot veto our voices, you cannot veto the truth, you cannot veto our principles, you cannot veto the Ukrainian people."
The wording of the draft text put before the Security Council was watered down in the hours before the vote to gain more support.
The word "condemns" was replaced by "deplores" and a reference to Chapter 7 of the UN Charter, which allows members to take military action to restore peace, was deleted.
The resolution reaffirmed the sovereignty of Ukraine and called for Russia to "immediately cease its use of force against Ukraine."
Ultimately, almost 70 countries co-sponsored the resolution.
"Make no mistake, Russia is isolated. It has no support for the invasion of Ukraine," said Britain's ambassador to the UN, Barbara Woodward.
Before the vote, Ms Thomas-Greenfield described Russia's attack as "so bold, so brazen, that it threatens our international system as we know it".
"We have a solemn obligation to not look away ... At the very minimum, we have an obligation to object," she said.
"Vote yes if you believe Russia should be held to account for its actions. Vote no or abstain if you do not uphold the charter and align yourselves with the aggressive and unprovoked actions of Russia.
"Just as Russia had a choice. So do you," she pleaded.
People look at the damage following a rocket attack in Kyiv, Friday, February 25, 2022. Source: AP / Emilio Morenatti/AP
Russia, which currently holds the rotating Security Council presidency, will likely face another vote on a similar resolution before the wider UN General Assembly which is all formed of all 193 member countries.
Moscow does not have a veto there and the resolution could be passed by a substantial margin, although it would be non-binding.
The General Assembly held a similar vote in 2014 condemning Russia's seizure of Crimea, which obtained 100 votes in support.
Moscow had earlier vetoed a Security Council resolution condemning its actions in Crimea. Thirteen countries supported it with China abstaining.
Following the vote, Ukrainian President Volodymyr Zelenskyy thanked the countries that voted for the resolution, saying they voted to "stop treacherous attack on & Charter. The veto of Russia is a bloodstain on its plaque in the Security Council, the map of Europe and the world. Anti-war coalition must act immediately!".
